Six impossible things before breakfast

Six impossible things before breakfast

Six impossible things before breakfast Batteries International

Tom Murphy opinionMay 10, 2015: Tom Murphy, associate professor of physics at the University of California, San Diego, takes a US perspective to show that an electricity supply from 100% renewable energy sources and using batteries as a back-up is not just impractical but impossible. Time to do our sums.

As we look to transition away from fossil fuels, solar and wind are attractive options. Key factors making them compelling are: the inexhaustibility of the source with use (they are renewable); their low carbon footprint; and the independence that small-scale distribution can foster (I’ll never put a nuclear plant on my roof, even if it would make me the coolest physicist ever!).

But solar and wind suffer a serious problem in that they are not always available. There are windless days, there are sunless nights, and worst of all, there are windless nights. Obviously, this calls for energy storage, allowing us to collect the energy when we can, and use it when we want.

Small-scale off-grid solar and wind installations have been doing this for a long time, typically using lead acid batteries as the storage medium. I myself have four golf-cart batteries in my garage storing the energy from eight 130 W solar panels, and use these to power the majority of my electricity consumption at home.

It’s worth pausing to appreciate this fact. Compare this scheme to the dream source of fusion. Why do people go ga-ga over fusion? Because there is enough deuterium in water to provide a seemingly inexhaustible source of energy, and there are no atmospheric emissions in the process.

Meanwhile, solar provides a source that will last longer (billions of years), produces even less pollution (no radioactive contamination of containment vessel), and is here today! It’s even affordable enough and low-tech enough to be on my roof and in my garage! People—we have arrived!

Storage works on the small scale, as many stand-aloners can attest. How would it scale up? Can it?

Meeting requirements

So what would it take? In the US, we’re not a nation tolerant of power outages. Those big refrigerators can spoil a lot of food when the electricity drops away. A rule of thumb for remote solar installations is that you should design your storage to last for a minimum of three days with no energy input. Even then, sometimes you will “go dark” in the worst storm of the winter.

This does not mean literally three days of total deprivation, but could be four consecutive days at 25% average input, so that you only haul in one day’s worth over a four day period, leaving yourself short by three.

So let’s buy ourselves security and design a battery that can last a week without any new inputs (as before this is not literally seven days of zero input, but could be eight days at 12.5% average input, or 10 days at 30% input). This may be able to manage the worst-case “perfect” storm of persistent clouds in the desert Southwest plus weak wind in the Plains.

Let’s also plan ahead and have all of our country’s energy needs met by this system: transportation, heating, industry. The rate at which we currently use energy in all forms in the US is 3 TW.

If we transition everything to electricity, we can get by with 2TW, assuming no growth in demand. Why? Because we currently use two-thirds of our energy supply (or 2TW) to run heat engines, getting only about 0.6TW out for useful purposes in the bargain. An electrical system could deliver this same 0.6TW for only 1TW of input, considering storage and transmission efficiencies.

Running a 2TW electrified country for seven days requires 336 billion kWh of storage. We could also use nuclear power as a base load to offset a significant portion of the need for storage — perhaps chopping the need in two. This post deals with the narrower topic of what it would take to implement a full-scale renewable-energy battery.
Scale the result as you see fit.

Lead acid delivers

I’ll use lead acid batteries as a baseline. Why? Because lead acid batteries are the cheapest way to store electricity today. They’re bulky, sloshy, and very heavy, which makes them unsuitable for electric cars or laptop computers. But they’re very efficient, commonly achieving 85% or better energy efficiency in a charge cycle.

The technology is well tested, having been around since 1859. And lead is a common element, being the endpoint of the alpha-decay chain of heavy elements like uranium and thorium. Their economic favorability makes lead acid batteries hands-down the most common battery type in stand-alone renewable systems worldwide.

Large lead acid batteries occupy a volume of 0.013 cubic metres (13 litres) per kWh of storage, weigh 25 kg/kWh (55 lb/kWh), and contain about 15 kg of lead per kWh of storage.

How do we put this into more familiar terms? A 12V battery rated at 200Ah of charge capacity stores 2,400Wh, or 2.4 kWh. 200Ah means that the battery could discharge a 10A current (120W) for 20 hours, or a one amp current (12W) for 200 hours—though in actual practice the capacity is lower at higher currents.

I can’t resist the temptation to ask: what is the minimum amount of lead that is theoretically needed to build the battery? The chemical reaction for a lead acid battery is such that each interaction involving the transformation of one lead atom to PbSO4 liberates one electron at a 2.1-volt potential. This electron then is bestowed 2.1 electron-volts (eV) of energy, amounting to 3.4×10−19 J . One kilowatt-hour is 3.6 million Joules (1,000 W times 3,600 seconds), so that it takes 1025 lead atoms (where every one participates).

If you remember that Avogadro’s number is 6×1023, we need about 20 moles of lead atoms. At 207 g/mol, this comes out to about 4 kg per kWh of energy, which is a factor of four less than the realized value above.

Real implementations always fall short of theoretical ideals, so this isn’t new. We would do well to push for future improvements on this score, although we should bear in mind that lead acid has had 150 years of development before we get carried away by dreams of perfection.

The US national battery

opinion-Alice pic2Putting the pieces together, our national battery occupies a volume of 4.4 billion cubic meters, equivalent to a cube 1.6 km (one mile) on a side. The size in itself is not a problem: we’d naturally break up the battery and distribute it around the country.

But this battery would demand 5 trillion kg (5 billion tons) of lead.

A USGS report from 2011 reports 80 million tons of lead in known reserves worldwide, with 7 million tons in the US.
A note in the report indicates that the recent demonstration of lead associated with zinc, silver, and copper deposits places the estimated (undiscovered) lead resources of the world at 1.5 billion tons. That’s still not enough to build the battery for the US alone. We could choose to be optimistic and assume that more lead will be identified over time.
But let’s not ignore completely the fact that at this moment in time, no one can point to a map of the world and tell you where even 2% of the necessary lead would come from to build a lead acid battery big enough for the US. And even the undiscovered, but suspected lead falls short.

What about cost? At today’s price for lead, $2.50/kg, the national battery would cost $13 trillion in lead alone, and perhaps double this to fashion the raw materials into a battery. Today’s deep cycle batteries retail for four times the cost of the lead within them.

But I guarantee that if we really want to use more lead than we presently estimate to exist in deposits, we’re not dealing with today’s prices. Leaving this caveat aside, the naïve $25 trillion price tag is more than the annual US GDP.

Recall that lead acid is currently the cheapest battery technology. Even if we sacrificed 5% of our GDP to build this battery (would be viewed as a huge sacrifice; nearly a trillion bucks a year), the project would take decades to complete.

But even then, we aren’t done: batteries are good for only so many cycles — roughly 1000, depending on the depth of discharge —so the national battery would require a rotating service schedule to recycle each part once every five years or so. This servicing would be a massive, expensive, and never-ending undertaking.

Who needs lead acid?

I focus here on lead acid because it’s the devil we know, it’s the cheapest storage at present, and the materials are far more abundant than lithium (13 million tons reserves worldwide, 33 million tons estimated global resources), or nickel (76 million tons global reserves, 130 million tons estimated land resources worldwide).

If we ever got serious about building big storage, there will be choices other than lead acid. But I nonetheless find it immensely instructive and daunting to understand what it would mean to scale a mature technology to meet our needs.

It worries me that the cheapest solution we have today would break the bank just based on today’s cost of raw materials, and that we can’t even identify enough in the world to get the job done.

This article does not proclaim that there is no way to build adequate storage to accommodate a fully-renewable energy infrastructure. A distributed grid helps, and an armada of gas-fired peak-load plants would offset the need for full storage. Storage can be augmented by pumped hydro, compressed air, flywheels, other battery technologies, etc.
Rather, the lesson is that we must work within serious constraints to meet future demands. We can’t just scale up the current go-to solution for renewable energy storage — we are yet again fresh out of silver bullet solutions.

More generally, large scale energy storage is not a solved problem. We should be careful not to trivialize the issues, which tends to reduce the imperative to work like mad on establishing adequate capabilities in time (requires decades of fore-thought and planning).